A comparison of PM exposure related to emission hotspots in a hot and humid urban environment: Concentrations, compositions, respiratory deposition, and potential health risks

Particle number concentration, particle size distribution, and size-dependent chemical compositions were measured at a bus stop, alongside a high way, and at an industrial site in a tropical city. It was found that the industry case had 4.93 × 107–7.23 × 107 and 3.44 × 104–3.69 × 104 #/m3 higher concentration of particles than the bus stop and highway cases in the range of 0.25–0.65 μm and 2.5–32 μm, respectively, while the highway case had 6.01 × 105 and 1.86 × 103 #/m3 higher concentration of particles than the bus stop case in the range of 0.5–1.0 μm and 5.0–32 μm, respectively. Al, Fe, Na, and Zn were the most abundant particulate inorganic elements for the traffic-related cases, while Zn, Mn, Fe, and Pb were abundant for the industry case. Existing respiratory deposition models were employed to analyze particle and element deposition distributions in the human respiratory system with respect to some potential exposure scenarios related to bus stop, highway, and industry, respectively. It was shown that particles of 0–0.25 μm and 2.5–10.0 μm accounted for around 74%, 74%, and 70% of the particles penetrating into the lung region, respectively. The respiratory deposition rates of Cr and Ni were 170 and 220 ng/day, and 55 and 140 ng/day for the highway and industry scenarios, respectively. Health risk assessment was conducted following the US EPA supplemented guidance to estimate the risk of inhalation exposure to the selected elements (i.e. Cr, Mn, Ni, Pb, Se, and Zn) for the three scenarios. It was suggested that Cr poses a potential carcinogenic risk with the excess lifetime cancer risk (ELCR) of 2.1–98 × 10− 5 for the scenarios. Mn poses a potential non-carcinogenic risk in the industry scenario with the hazard quotient (HQ) of 0.98. Both Ni and Mn may pose potential non-carcinogenic risk for people who are involved with all the three exposure scenarios

Biomass gasification for syngas and biochar co-production: Energy application and economic evaluation

Syngas and biochar are two main products from biomass gasification. To facilitate the optimization of the energy efficiency and economic viability of gasification systems, a comprehensive fixed-bed gasification model has been developed to predict the product rate and quality of both biochar and syngas. A coupled transient representative particle and fix-bed model was developed to describe the entire fixed-bed in the flow direction of primary air. A three-region approach has been incorporated into the model, which divided the reactor into three regions in terms of different fluid velocity profiles, i.e. natural convection region, mixed convection region, and forced convection region, respectively. The model could provide accurate predictions against experimental data with a deviation generally smaller than 10%. The model is applicable for efficient analysis of fixed-bed biomass gasification under variable operating conditions, such as equivalence ratio, moisture content of feedstock, and air inlet location. The optimal equivalence ratio was found to be 0.25 for maximizing the economic benefits of the gasification process

Stability of Granular Materials under Vertical Vibrations

The influence of periodic vibrations on the granular flow of materials is of great interests to scientists and engineers due to both theoretical and practical reasons. In this paper, the stability of a vertically vibrated granular layer is examined by linear stability analysis. This includes two major steps, firstly, the base state at various values of mass holdup (Mt) and energy input (Qt) is calculated and secondly, small perturbations are introduced to verify the stability of the base state by solving the resultant eigenvalue problem derived from the linearized governing equations and corresponding boundary conditions. Results from the base state solution show that, for a given pair of Mt and Qt, solid fraction tends to increase at first along the layer height and then decrease after a certain vertical position while granular temperature decreases rapidly from the bottom plate to the top surface. This may be due to the existence of inelastic collisions between particles that dissipate the energy input from the bottom. It is also found that more energy input results in a lower solid fraction and a higher granular temperature. The stability diagram is constructed by checking the stability property at different points in the Mt-Qt plane. For a fixed Mt, the base state is stable at low energy inputs, and becomes unstable if Qt is larger than a critical value Qtc1. A higher value of Mt corresponds to a larger Qtc1. There also exists a critical mass holdup (Mtc), for Mt larger than Mtc, the patterns corresponding to the instabilities are standing waves (stationary mode); otherwise the flat layer appears (layer mode). Moreover, the stationary mode turns into the layer mode when Qt is increased beyond a critical value Qtc2. These findings agree with the experimental observations of other researchers (Hsiau and Pan, 1998). The effects of restitution coefficients (ep, ew) and material properties (dp, ρp) on the stability diagram are also investigated. Together with Mt and Qt these variables can be classified into two groups, i.e. the stabilizing factors (Mt, dp, ρp) and the destabilizing factors (Qt, ep, ew). The stability of the system is enhanced with increasing stabilizing factors and decreasing destabilizing factors.Singapore-MIT Alliance (SMA

Comparison of the co-gasification of sewage sludge and food wastes and cost-benefit analysis of gasification- and incineration-based waste treatment schemes

The compositions of food wastes and their co-gasification producer gas were compared with the existing data of sewage sludge. Results showed that food wastes are more favorable than sewage sludge for co-gasification based on residue generation and energy output. Two decentralized gasification-based schemes were proposed to dispose of the sewage sludge and food wastes in Singapore. Monte Carlo simulation-based cost-benefit analysis was conducted to compare the proposed schemes with the existing incineration-based scheme. It was found that the gasification-based schemes are financially superior to the incineration-based scheme based on the data of net present value (NPV), benefit-cost ratio (BCR), and internal rate of return (IRR). Sensitivity analysis was conducted to suggest effective measures to improve the economics of the schemes

Multiphysics Simulation in Drug Development and Delivery

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On the Electrostatics of Pneumatic Conveying of Granular Materials

In this work the electrostatics of the pneumatic conveying of granular materials in a non-conducting (PVC) vertical pipe is studied using Electrical Capacitance Tomography (ECT) system. The non-conducting wall in general attains static charges arising from particle-wall collisions in the initial periods of conveying process and then reaches equilibrium with the surroundings. The polarity of particles and conveying pipe inner wall agrees reasonably well with the contact potential difference measurements. The perturbations in the capacitance signal due to charge accumulation are larger with smaller air superficial velocity. The denser flow regimes give larger wall residual charge. Wall charging process shows similar trend by surface potential and ECT measurements. The addition of small amount (0.5% by weight) of anti-static agent (Larostat-519) in the powder form decreases the electrostatic charge generation by altering the patterns for particle-particle and particle-wall collisions.Singapore-MIT Alliance (SMA

Variation of household electricity consumption and potential impact of outdoor PM2.5 concentration: a comparison between Singapore and Shanghai

The auto-regressive distributed lag (ARDL) bound testing approach was used to study the relationships between the monthly household electricity consumption and outdoor PM2.5 concentration with the consideration of ambient temperature and the number of rainy days for Singapore and Shanghai. It is shown that there are significant long-run relationships between the household electricity consumption and the regressors for both Singapore and Shanghai. For Singapore, a 20% increase in the PM2.5 concentration of a single month is in the long-run significantly related to a 0.8% increase in the household electricity consumption. This corresponds to an electricity overconsumption of 5.0 GWh, a total of 0.7–1.0 million USD in electricity cost, and 2.1 kilotons of CO2 emission associated with electricity generation. For Shanghai, a 20% decrease in the PM2.5 concentration of a single month is in the long-run significantly related to a 2.2% decrease in the household electricity consumption. This corresponds to a 35.0 GWh decrease in the overall household electricity consumption, 1.6–5.1 million USD decrease in electricity cost, and 17.5 kilotons of CO2 emission. The results suggest that the cost of electricity consumption should be included in the economic cost analysis of PM2.5 pollution in the future. A 1 °C increase in the monthly temperature is in the long-run significantly related to a 13.6% increase in the monthly electricity consumption for Singapore, while a 30 degree days increase in heating & cooling days (HCDD) is in the long-run significantly related to a 24.9% increase in the monthly electricity consumption for Shanghai. A 5-day increase in the number of rainy days per month is in the long-run significantly related to a 3.0% and 5.8% increase in the monthly electricity consumption for Singapore and Shanghai, respectively

On the association between outdoor PM 2.5 concentration and the seasonality of tuberculosis for Beijing and Hong Kong

Tuberculosis (TB) is still a serious public health problem in various countries. One of the long-elusive but critical questions about TB is what the risk factors are and how they contribute for its seasonality. An ecologic study was conducted to examine the association between the variation of outdoor PM2.5 concentration and the TB seasonality based on the monthly TB notification and PM2.5 concentration data of Hong Kong and Beijing. Both descriptive analysis and Poisson regression analysis suggested that the outdoor PM2.5 concentration could be a potential risk factor for the seasonality of TB disease. The significant relationship between the number of TB cases and PM2.5 concentration was not changed when regression models were adjusted by sunshine duration, a potential confounder. The regression analysis showed that a 10 μg/m3 increase in PM2.5 concentrations during winter is significantly associated with a 3% (i.e. 18 and 14 cases for Beijing and Hong Kong, respectively) increase in the number of TB cases notified during the coming spring or summer for both Beijing and Hong Kong. Three potential mechanisms were proposed to explain the significant relationship: (1) increased PM2.5 exposure increases host's susceptibility to TB disease by impairing or modifying the immunology of the human respiratory system; (2) increased indoor activities during high outdoor PM2.5 episodes leads to an increase in human contact and thus the risk of TB transmission; (3) the seasonal change of PM2.5 concentration is correlated with the variation of other potential risk factors of TB seasonality. Preliminary evidence from the analysis of this work favors the first mechanism about the PM2.5 exposure-induced immunity impairment. This work adds new horizons to the explanation of the TB seasonality and improves our understanding of the potential mechanisms affecting TB incidence, which benefits the prevention and control of TB disease

Techno-economic and greenhouse gas savings assessment of decentralized biomass gasification for electrifying the rural areas of Indonesia

This study explored the feasibility of decentralized gasification of oil palm biomass in Indonesia to relieve its over-dependence on fossil fuel-based power generation and facilitate the electrification of its rural areas. The techno-feasibility of the gasification of oil palm biomass was first evaluated by reviewing existing literature. Subsequently, two scenarios (V1 and V2, and M1 and M2) were proposed regarding the use cases of the village and mill, respectively. The capacity of the gasification systems in the V1 and M1 scenarios are determined by the total amount of oil palm biomass available in the village and mill, respectively. The capacity of the gasification systems in the V2 and M2 scenarios is determined by the respective electricity demand of the village and mill. The global warming impact and economic feasibility (net present value (NPV) and levelized cost of electricity (LCOE)) of the proposed systems were compared with that of the current practices (diesel generator for the village use case and biomass boiler combustion for the mill use case) using life cycle assessment (LCA) and cost-benefit analysis (CBA). Under the current daily demand per household (0.4 kWh), deploying the V2 system in 104 villages with 500 households each could save up to 17.9 thousand tons of CO2-eq per year compared to the current diesel-based practice. If the electricity could be fed into the national grid, the M1 system with 100% capacity factor could provide yearly GHG emissions mitigation of 5.8 × 104 ton CO2-eq, relative to the current boiler combustion-based reference scenario. M1 had a positive mean NPV if the electricity could be fed into the national grid, while M2 had a positive mean NPV at the biochar price of 500 USD/ton. Under the current electricity tariff (ET) (0.11 kWh) and the biochar price of 2650 USD/ton, daily household demands of 2 and 1.8 kWh were required to reach the break-even point of the mean NPV for the V2 system for the cases of 300 and 500 households, respectively. The average LCOE of V2 is approximately one-fourth that of the reference scenario, while the average LCOE of V1 is larger than that of the reference scenario. The average LCOE of M1 decreased to around 0.06 USD/kWh for the case of a 100% capacity factor. Sensitivity analysis showed that the capital cost of gasification system and its overall electrical efficiency had the most significant effects on the NPV. Finally, practical system deployment was discussed, with consideration of policy formulation and fiscal incentives

Bubble Behavior in a Taylor Vortex

We present an experimental study on the behavior of bubbles captured in a Taylor vortex. The gap between a rotating inner cylinder and a stationary outer cylinder is filled with a Newtonian mineral oil. Beyond a critical rotation speed (ω[subscript c]), Taylor vortices appear in this system. Small air bubbles are introduced into the gap through a needle connected to a syringe pump. These are then captured in the cores of the vortices (core bubble) and in the outflow regions along the inner cylinder (wall bubble). The flow field is measured with a two-dimensional particle imaging velocimetry (PIV) system. The motion of the bubbles is monitored by using a high speed video camera. It has been found that, if the core bubbles are all of the same size, a bubble ring forms at the center of the vortex such that bubbles are azimuthally uniformly distributed. There is a saturation number (N[subscript s]) of bubbles in the ring, such that the addition of one more bubble leads eventually to a coalescence and a subsequent complicated evolution. Ns increases with increasing rotation speed and decreasing bubble size. For bubbles of non-uniform size, small bubbles and large bubbles in nearly the same orbit can be observed to cross due to their different circulating speeds. The wall bubbles, however, do not become uniformly distributed, but instead form short bubble-chains which might eventually evolve into large bubbles. The motion of droplets and particles in a Taylor vortex was also investigated. As with bubbles, droplets and particles align into a ring structure at low rotation speeds, but the saturation number is much smaller. Moreover, at high rotation speeds, droplets and particles exhibit a characteristic periodic oscillation in the axial, radial and tangential directions due to their inertia. In addition, experiments with non-spherical particles show that they behave rather similarly. This study provides a better understanding of particulate behavior in vortex flow structures.Singapore-MIT Alliance (SMA